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Chemical Polishing Agent for Stainless Steel

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2007-10-21
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Introduce:

Adopting Chemical polishing agent from Japan; remove away 0.005mm raised surface(Ra≤0.05) on stainless steel through soaking methods,i.e.tiny burr, raw edge, acute angle. Its polishing capacity can obtain mirror level; surface is completely passivated with changing physical & chemical nature.Its surface has obvious smoothness, polishing, anticorrosion, adhesion resistance, beautiful appearance, cleanliness, sanitation.Its effect is better than electrolytic chemical polishing with low cost. It's applied for spaceflight, aviation, medical-treatment apparatus, chemcial equipment, electron, electric appliance, foods & pharmacy equipment, hardware parts, decoration and so on.

Technologic Feature: 字串1

1 , abrasive & polishing for Austenitic stainless steel: SUS304 , 321 , 303 , 316 , 316L

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2 , not containing hydrofluoric acid, lower than 5% for acid-mist density.

3 , polishing pipe interior for stainless steel.
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Feature:

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1 , State: Liquid 字串4

2 , Color: Yellow or Milk White 字串5

3 , Taste: no special smell

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4 , Toxicity: innocuity

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5 , Weight : 1.02

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Abrasive Treatment Capacity

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1, According to different working surface and material,different polishing area for processing state, luster demand, treatment time; according to normal operation process,abrasive area for 1L abrasive mixing liquid,as follows:
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Stainless Steel 字串9

Polishing Treatment Time 字串4

Polishing Area

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  SUS304/303/321 字串2

     3 Minute 字串5

     0.288M2 字串6

5 Minute 字串1

     0.18M2 字串3

10 Minute

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     0.07M2

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  SUS316/316L 字串1

3 Minute 字串5

     0.14M2 字串5

5 Minute 字串6

     0.09M2

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10 Minute

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     0.07M2 字串7

2, Depending on the following factors for surface area of abrasive polishing metal

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( 1 ) original surface state

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( 2 ) quality demand for processing surface

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( 3 ) polishing time
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Instruction: 字串4

atment before polishing: 字串8

1, Absorbent Dirt Removal:remove light adhesion:lubricant, polishing agent, dirt and so on. 字串2

2, deoxidized layer:remove oxidized peel on stainless-steel surface for rolling, extension, , crimping, punching, weld. 字串7

3, Container:glass, porcelain, titanic material, hearproof, aticorrosive vessel with glass fibre reinforced plastic; 1 time than volume of polishing solution.

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4, Temperature:heat to 9 5℃ with liquefier or heating wire, when bubble boiling,add up a small quantity of bubble-removing agent.. 字串4

5, Polishing:lightly put polished workpiece into polishing solution in full soaking,vibrate workpiece for complete contact with polishing agent,then take them out according to instruction,wash it with water immediately.

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Notice:

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1, For complicated shape, when put the parts once,mix them enough to avoid mutual adhesion. 字串7

2, Before using polishing solution,check the area for stainless-steel parts. 字串6

3, When not obvious luster or dirt spot,exchage polishing agent on time.

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4, Protective glass, veil, anticide glove, apron, rubber boots for operator

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5, Avoid to direct irradiation from sun, put polished parts in ventilative shades. 字串4

the Theory for Chemical Polishing : 字串8

h the parts on metal suface through soaking, changing physical & chemical property for passivation.Greatly improve the smoothness, luster, anticorrosion, adhesion resistance, beauty, sanitation on surface.Remove raised surface in 0.005mm,change the roughness, get rid of tiny burr,polish precision parts. No need of complicated equipment in short time for batch treatment,Better than electrolytic chemical polishing on effect.
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Introduction 字串2

People think that stainless steel can't rust forever. However,stainless steel, the same as other metals,easily affected by the environment for hand & air contact. Besides,the surface can form tiny burr and raw edge; black oxidated layer through machinery processing,such as weld, pressing, crimp, heat treatment and so on. Generally it's difficult to remove them,easy to affect the exertion from workpiece. To settle the problems, people make polishing treatment on stainless-steel surface with different methods,as follows: 字串4

     1, Machinery Polishing:

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     a: grinding wheel b: spray sand c: grinding d: extrusion    

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   2  Chemical Polishing:

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      a. electrolytic chemical; b. chemical             

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     3, Compound Polishing:       integration with nachinery polishing and chemical polishing 字串5

         For different metals , using occasions, memands on metal surfance,we must make polishing treatment with different methods to satisfy it. 字串9

2 ,   difference between chemical polishing, electrolytic polishing and machinery polishing 字串2

 (1) Comparison from Chemical Polishing and Machinery Polishing 字串5

    Chemical Polishing:firstly resolve tiny bulge to improve the roughness on metal surface 字串8

    Machinery Polishing:cut and grind bulge to improve the smoothness and luster. 字串3

     Different effects on metal surface for two kinds of polishing,changed property on metal surface.For the limitation of machinery polishing,it can't display effective function from metal workpiece. In the 1980's,new technique---electrolytic chemical polishing took on us,which has more obvious superiority than machinery polishing.But it still has some disadvantage

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  ( 2 ) Comparison from Chemical Polishing and Electrolytic Polishing

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     ★ Chemical Polishing:soak metal in special chemical solution,natually resolve metal surface on chemical energy.

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     ★ Electrolytic Chemical Polishing:soak metal in special solution,resolve metal surface on anode of current energy to obtain smooth surface.

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Chemical polishing is only simple soaking operation; electrolytic polishing is complicated on operation: large capacity of direct current,difficult quality control and treatment on special workpiece. Comparing with electrolytic polishing,chemical polishing technique can't satisfy importmant indexes,such as luster environmental protection, polishing effect. 字串8

 

Chemical Rubbing 字串4

Electrolytic Chemical Rubbing

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Machinery Rubbing 字串6

1

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Obtaining lucent polishing surface on rubbed parts with chemical reaction dissolvent

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Obtaining lucent polishing surface on rubbed parts with anode dissolvent of electrochemical reaction

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Obtaining lucent polishing surface on rubbed parts with cutting, transfiguration, abrasion 字串4

2 字串2

Form protective layer through chemical reaction for rubbed surface, improve anticorrosion, abrasion resistance with lasting luster. 字串4

Equal to the left

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Form indurative layer and crystal lattice structure for transfiguration, lessen anticorrosion and abrasion resistance, no lasting luster for oxidation.

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3 字串8

Small smooth resistance on roughness, lasting smooth on rubbed surface

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Equal to the left
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Large smooth resistance on roughness,no lasting smooth on rubber surface 字串3

4 字串3

No adhesion on rubber surface

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Equal to the left
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Impurity adhesion on rubber surface:metal granule, sand granule, rubbed, rubbed stearic and so on 字串1

5 字串5

Easily remove tiny burr on rubbed surface(below 100μm)
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Difficultly remove tiny burr on rubber surface(beyond 100μm) 字串6

Difficultly remove tiny burr on rubber surface(beyond 100μm) 字串4

6

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Good reflex on rubbed surface,high refleting engergy, over 90% on positive reflecting rate
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Equal to the left
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Low reflecting energy for unorderly refex, 60% on positive reflecting rate 字串2

7 字串2

No stress transfiguration on rubbed workpiece

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Equal to the left

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Stress transfiguration on workpiece after processing

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8 字串4

Increse 10~20% on antifatigue strength for small surface difference

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Equal to the left
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Fatigue strength

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9

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For electric substance,improve cold irradiation arc sparkle on contact surface to increase electric capability
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Equal to the left

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Bring about sparkle arc for raw edge

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10

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Polish any sheet metal no matter complicated workpiece

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No treatment for workpiece for electric current

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Difficult to polish the workpiece with special shape
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11 字串4

Short time for polishing treatment

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Long time for polishing treatment

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Long time for polishing treatment 字串4

12

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Extemely simple operational technique

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Complicated technical operation

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Difference from operational technician 字串4

13

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Batch processing for small workpiece

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No volume-production for workpiece

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No volume-production for workpiece 字串4

14 字串2

Small investment on equipment 字串2

Large investment on equipment and technician

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A certain investment on equipment 字串5

15

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No need of electric energy

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Large electric energy 字串1

Small electric energy

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16 字串5

Unserious environmental pollution

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Serious environmental pollution

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Serious environmental pollution
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17 字串3

not remove deep nick for on polished surface 字串4

Equal to the left

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remove deep nick for a certain time through the treatment

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18

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no treatment for some materials 字串6

Equal to the left 字串2

no effect from any meterial
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19

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Difficult for large workpiece

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Relatively difficult for large workpiece

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Treatment for large workpiece

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20 字串4

Strong Dependence on medicine

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Accessible chemical polishing solution, 字串6

No disadvantage 字串2

21

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Medium Cost

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High Cost

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Low Cost 字串5

3 , the Theory for Chemical Polishing Reaction 字串8

   Many scholars think that metal surface from chemical rubbing brings about partical electromotive force to form chemical resolvent for partial density difference, temperature difference, uneven resolved PH indicator.Electrolytic chemical rubbing bring about partical electromotive force to form chemical resolvent on external power(current distribution). There are many similarities between metal surface for chemical rubbing and electrolytic rubbing.People ususally think chemcial rubbing is the same as electrolytic rubbing on reaction mechanism for chemical natural resolvent and chemical anode resolvent. It's significant to develop chemical rubbing further.

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( 1 )           Introduction for Reaction Mechanism Theory

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    On chemical rubbing,it hasn't been uncertain about absolutely unified theory for many unclear contents. 字串1

1, Different unsmooth resistance for current distribution 字串2

2, Molecular diffused speed theory

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3, Distribution from partial electromotive force 字串3

4, Machniery destroyed theory 字串5

   a.Bring about large numbers of bubbles on rubbed surface for gas liquid effect; bring about machinery function when raised bubble deviation; dissolved by rubbing solution on destroyed surface.

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   b.Tension effect on surface, easliy changed tension on raised surface; destroyed and dissolved by rubbing solution on partial solution layer 字串2

5, Active partial chemical reaction 字串8

6, Surface crystal lattice theory: difference between crystal lattice

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7, Porous oxidation film theory:different film permeation

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    Although different explanation for chemical rubbing between above-mentioned theory, it's recognized for scholars to bring about smooth surface after ressolving tiny bulge on metal surface. 字串4

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(2)Chemical Rubbing Mechanism Theory

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V= D(C o -C e ) / b 字串9

  Diffused Speed: V diffused layer: b

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  Diffused speed coefficient: D

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  Metal ionic density in chemical rubbing solution: C o

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  Metal ionic density on metallic surface: C e 字串7

  Thickness of concave diffused layer : V , small reaction resolvent

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  Thickness of concave diffused layer : V , small reaction resolvent

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( 2 )     Chemical Rubbing Burring Theory 字串2